Aqueous processing method for flexographic printing plates

ABSTRACT

A system is for processing a photosensitive flexographic printing plate having a latent image formed by image-wise exposure of an aqueous-processable photopolymer. The system can use a first aqueous processing solution with the latent image for cleaning and then washing a resulting relief image with a second aqueous processing solution, where the second aqueous processing solution is devoid of the photopolymer. A processing solution tank is configured to combine the first used aqueous processing solution with the second used aqueous processing solution to form a combined used aqueous processing solution. A processing solution removal can include: a holding tank configured for receiving the combined used aqueous processing solution; and a conduit from the processing solution tank to the holding tank. The processing solution tank includes the combined used aqueous processing solution at less than a predefined maximum volume and having the photopolymer at less than a predefined maximum concentration.

CROSS-REFERENCE TO RELATED APPLICATIONS

This patent application is a divisional application of U.S. patentapplication Ser. No. 16/422,518 filed May 24, 2019, which is acontinuation application of U.S. patent application Ser. No. 15/196,122filed Jun. 29, 2016, which applications are incorporated herein byspecific reference in their entirety.

FIELD OF THE INVENTION

This invention pertains to the field of flexographic printing, and moreparticularly to an aqueous processing method for flexographic printingplates.

BACKGROUND OF THE INVENTION

Relief printing plates, such as flexographic plates, falls into two maincategories: (1) those that are processed using aqueous solutions toremove unexposed photopolymer, and (2) those that need to be processedusing some other chemical solvent. In recent years, flexographicprinting plates using an aqueous-processable photopolymer are gainingmore market interest because of their environmentally-friendlycharacteristics. They have the additional advantage that they can reduceorganic solvent exposure at the workplace. Aqueous-processable printingplates are sometimes referred to as aqueous-washable printing platesbecause the processing typically involves washing off the unexposedphotopolymer.

There are also two main types of aqueous-processable flexographicprinting plates: (1) those that are processable by dissolution of thephotopolymer using a strong alkaline solution (i.e., having a pH>11),and (2) those that are processable by dispersion of the photopolymerusing a processing solution including a dispersing agent (typicallyhaving a pH<11).

Aqueous-processable flexographic printing plates may be processed (i.e.,“washed”) by a number of methods. For example, U.S. Pat. No. 5,124,736(Yamamoto et al.), entitled “Process and apparatus for developingphotopolymer plate,” describe systems which form the relief by sprayingprocessing solution (i.e., “washout solution”) under pressure onto theprinting plate, and systems which form the relief by rubbing a brushagainst the printing plate in the presence of the processing solution,thereby dissolving the unexposed portions in the processing solution.Yamamoto et al., describe a system in which processing solution isfiltered and recirculated to the plate processor after a full batch ofplatemaking.

As noted by U.S. Pat. No. 6,247,856 (Shibano et al.), entitled“Developing system of photosensitive resin plates and apparatus usedtherein,” photopolymer (i.e., resin) can build up in the used processingsolution after processing a number of printing plates. This can causevarious problems, such as decreasing the speed of development, and thedispersed resin forming scum which adheres to the plates and the brush.This can require frequent disposal of the used processing solution andpreparation of a fresh processing solution. Shibano et al. discloses theaddition of fresh processing solution to a processing unit, whileremoving part of the resin-containing processing solution to keep theresin content of the processing solution substantially constant.

In order to remove debris that becomes attached to the surface of theprinting plate, a rinsing station can be employed after the main plateprocessing step. U.S. Patent Application Publication No. 2009/0013888(Danon), entitled “Methods and means relating to photopolymer printingplates,” discloses processing a printing plate using a processingsolution, followed by rinsing with water in a rinsing station. Usedprocessing solution is recycled back to the processor after filtration.Waste water from the rinsing station may also be recycled back to theprocessor after filtration.

U.S. Pat. No. 5,828,923 (Harabin et al.), entitled “Apparatus and methodfor processing water wash photopolymer solution,” disclose directingused processing solution into a holding tank, and adding a coagulant tocoagulate the solid content for disposal.

European Patent 0586470B1 (Danon), entitled “Preparation ofphotopolymerised elastomeric printing plates” disclose a processingsystem including (a) a wash-out section where unexposed areas of theplate are removed; (b) a rinse section; (c) an excess water-removingsection; (d) a light-finishing section where the plate is exposed by UVlight to reduce the stickiness of the plate surface; and (e) a dryingsection.

European patent 0586483B1 (Danon), entitled “Method and Apparatus forwashing-out printing plates,” discloses a system for processing printingplates where processing solution is directed through a spray bar alongdownwardly directed bristles of a washout brush.

It has been found that even when utilizing a plate processor thatincludes a rinse operation, such as that disclosed in the aforementionedU.S. Patent Application Publication No. 2009/0013888, there can still besignificant problems with plate defects after the production of only afew plates. The occurrence of plate defects is particularly problematicwith the increasingly popular photopolymer plates with includemicro-texture on the raised plate surface (i.e., the printing surface).As discussed in U.S. Pat. No. 8,399,177 (Stolt et al.), entitled“Enhanced printing plate,” the micro-texture is beneficial to enhanceprint density and uniformity. In such cases, the debris particles tendto accumulate on the micro-texture surface of the printing plate, whichresults in unacceptable print defects after processing a small number ofprinting plates.

There remains a need for an improved aqueous processing method forflexographic printing plates that enables processing a larger number ofdefect-free printing plates before it is necessary to replace the usedprocessing solution.

SUMMARY OF THE INVENTION

The present invention represents a method for processing aphotosensitive flexographic printing plate having a latent image formedby image-wise exposure of an aqueous-processable photopolymer,including:

using a main processing unit to develop the latent image into a reliefimage by removing unexposed photopolymer from the photosensitiveflexographic printing plate by contacting the photosensitiveflexographic printing plate with an aqueous processing solutionincluding a first dispersing agent while the photosensitive flexographicprinting plate is being subjected to mechanical cleaning, wherein theaqueous processing solution is supplied to the main processing unit froma processing solution tank, and wherein used aqueous processing solutioncontaining the removed photopolymer is returned from the main processingunit back into the processing solution tank;

using a secondary processing unit to wash the developed relief imagewith a secondary aqueous processing solution including a seconddispersing agent to remove debris from the developed relief image,wherein unused secondary aqueous processing solution is provided to thesecondary processing unit, and wherein used secondary aqueous processingsolution containing the removed photopolymer is directed from thesecondary processing unit into the processing solution tank; and

removing a portion of the aqueous processing solution from theprocessing solution tank to keep a volume of aqueous processing solutionin the processing solution tank below a predefined maximum volume;

wherein a concentration of photopolymer in the aqueous processingsolution in the processing solution tank is maintained below apredefined maximum photopolymer concentration.

This invention has the advantage that the quality of aqueous-processableprinting plates is improved by more effective removal polymerparticulates and debris that can cause print defects from the surface ofthe printing plate.

It has the further advantage that the productivity of plate making isimproved by extending the number of defect-free printing plates that canbe produced before a complete clean-out of the plate processor isrequired.

It has the additional benefit is the processing unit and holding tankare maintained in a cleaner state, which requires a shorter time for athorough clean-out of the plate processor.

BRIEF DESCRIPTION OF THE DRAWINGS

FIGS. 1A-1D illustrate the steps involved with forming a flexographicprinting plate according to an exemplary process;

FIG. 2 shows a schematic diagram of a system for processing aphotosensitive flexographic printing plate according to an exemplaryembodiment;

FIG. 3A shows a table summarizing the results of an experiment tocharacterize the performance of a prior art processing system; and

FIGS. 3B-3D show tables summarizing the results of experiments used tocharacterize processing systems using embodiments of the presentinvention.

It is to be understood that the attached drawings are for purposes ofillustrating the concepts of the invention and may not be to scale.Identical reference numerals have been used, where possible, todesignate identical features that are common to the figures.

DETAILED DESCRIPTION OF THE INVENTION

The invention is inclusive of combinations of the embodiments describedherein. References to “a particular embodiment” and the like refer tofeatures that are present in at least one embodiment of the invention.Separate references to “an embodiment” or “particular embodiments” orthe like do not necessarily refer to the same embodiment or embodiments;however, such embodiments are not mutually exclusive, unless soindicated or as are readily apparent to one of skill in the art. The useof singular or plural in referring to the “method” or “methods” and thelike is not limiting. It should be noted that, unless otherwiseexplicitly noted or required by context, the word “or” is used in thisdisclosure in a non-exclusive sense.

In accordance with the present invention, flexographic printing platesare formed by applying an aqueous processing solution to photosensitiveflexographic printing plate precursors having latent images formed in anaqueous-processable photopolymer. In an exemplary embodiment, thephotosensitive flexographic printing plates are similar to thosedescribed in U.S. Pat. No. 8,492,449 No. (Inoue et al.), entitled“Photosensitive resin composition, printing plate precursor andflexographic printing plate.” However, the described processing systemand method is applicable to other types of aqueous-processable printingplates, including other types of aqueous-processable relief printingplates (e.g., letterpress printing plates).

Before processing, a latent image is formed on the photosensitiveflexographic printing plate using any appropriate method known in theart. In an exemplary embodiment, the latent image is formed using a maskimage as described in commonly-assigned U.S. Pat. No. 9,250,527(Kidnie), entitled “Mask forming imageable material and use,” which isincorporated herein by reference. This method is illustrated in FIGS.1A-1D.

FIG. 1A illustrates a mask material 10, which includes a mask layer 12on a substrate 14. In an exemplary embodiment, the mask material 10 isthe commercially-available Kodak Flexcel NX Thermal Imaging Layermaterial. Further information about such mask materials 10 can be foundin the aforementioned U.S. Pat. No. 9,250,527. The mask layer 12 isopaque to the radiation that will be used to expose the photosensitiveflexographic printing plate (e.g., to UV radiation). The mask material10 is exposed to radiation 16 in an image-wise fashion to form a maskimage 18 in the mask layer 12. The mask image 18 will typically includepatterns of halftone dots, lines, text and solid areas (with or withoutmicro-surface patterning) according to the image content to be printed.In an exemplary embodiment, the radiation 16 is provided by acommercially-available Kodak Trendsetter NX Imager, which uses aninfrared laser to ablate portions of the mask layer 12 where it isdesired to produce raised features on the flexographic printing plate.

As illustrated in FIG. 1B, the mask material 10 is now laminated to aphotosensitive printing plate 20. The photosensitive printing plate 20includes a photosensitive photopolymer layer 22 over a substrate 24. Themask material 10 is laminated such that the mask layer 12 having themask image 18 faces the photopolymer layer 22. In an exemplaryembodiment, the photosensitive printing plate 20 is of a type similar tothose described in the aforementioned U.S. Pat. No. 8,492,449 (Inoue etal.) (except that no antiadhesive layer is included over thephotopolymer layer), and the lamination is performed (after removing thecover film from the photosensitive printing plate 20) using acommercially-available Kodak Flexcel NX laminator so that the maskmaterial 10 is in an intimate contact with the photopolymer layer 22 ofthe photosensitive printing plate 20.

In FIG. 1C, the laminated photosensitive printing plate 20 is exposed toradiation 26 to form a latent image 28 in the photopolymer layer 22.Various commercially available UV exposure devices may be used toperform this operation. In an exemplary embodiment, the radiation 26 isUV radiation supplied by a commercially-available Concept 302 EDLFsystem available from Mekrom Engineering. Where the mask image 18 hasbeen ablated, the radiation 26 passes through the mask layer 12 andexposes the photopolymer layer 22, thereby cross-linking and hardeningthe photopolymers to provide a developable latent image 28 includingcross-linked polymer regions 29. The UV exposure 26 can be provided at awide range of temperatures from about room temperature up to 60 C.However, it has been found that UV radiation exposure performed atelevated temperatures in the range of 42 C-52° C. provides better finalplate quality (e.g., improved minimum dot holding and better resolutionof surface micro-textures).

After the latent image 28 has been formed, the mask material 10 isremoved, and the photosensitive printing plate 20 is processed toprovide a developed relief image 30 as illustrated in FIG. 1D. Theprocessing operation (sometimes referred to as “developing the printingplate”) involves removing the unexposed portions of the photopolymerlayer where were not hardened by the radiation 26 (FIG. 1C) leaving thecross-linked polymer regions 29. In accordance with the presentinvention, the photopolymer layer 22 is made of an aqueous-processablephotopolymer so that the processing operation uses an aqueous processingsolution (i.e., a water-based processing solution), typically includingan active ingredient such as a dispersing agent. Aqueous processingsolutions are generally preferred to processing solutions using othersolvents (e.g., organic solvents) because of theirenvironmentally-friendly characteristics.

FIG. 2 shows a schematic diagram of an exemplary processing system 100for processing an aqueous-processable photosensitive printing plate 20in accordance with the present invention. In an exemplary embodiment,the photosensitive printing plate 20 is of a type similar to thosedescribed in the aforementioned U.S. Pat. No. 8,492,449 (Inoue et al.)(except that no antiadhesive layer is included over the photopolymerlayer). However, other types of aqueous-processable printing plates canalso be used.

In the exemplary arrangement of FIG. 2, the plate processing takes placeas an “in-line process” where the photosensitive printing plate 20proceeds through the processing system 100 along a processing path 101where a series of processing operations are applied. In alternateembodiments, the plate processing can be performed as a “batch process”,where after the main plate processing, the plate moves in the reversedirection and the secondary processing takes place similar to thein-line process.

In an exemplary arrangement, the photosensitive printing plate 20 ismounted on a platen 110 as it is moved along the processing path 101.The input to the processing system 100 is a photosensitive printingplate 20 having a latent image 28 formed by exposing the photopolymerlayer 22. The latent image 28 includes exposed portions 124 where thephotopolymer layer 22 has been hardened by exposure to appropriateactinic radiation, and unexposed portions 126 where the photopolymerlayer 22 remains soft and is to be removed from the substrate 24 duringprocessing.

Main processing unit 102 is used to develop the latent image 28 into arelief image 30 by removing the unexposed portions 126 of thephotopolymer layer 22 from the photosensitive printing plate 20. Themain processing unit 102 can also referred to as a processing station ora development unit/station. The main processing unit 102 includes a pump112 for drawing aqueous processing solution 142 from a processingsolution tank 140 and directing it through a series of pumps 114 tobring the aqueous processing solution 142 into contact with thephotosensitive printing plate 20.

The aqueous processing solution 142 includes a dispersing agent (i.e.,“soaps”) to aid in the removal of the unexposed photopolymer. Anyappropriate dispersing agent known in the art can be used in accordancewith the present invention. Some examples of appropriate dispersingagents are discussed in U.S. Pat. No. 9,005,884 (Yawata et al.),entitled “Developer composition for printing plate, developer and methodfor manufacturing printing plate,” which is incorporated herein byreference. In one example, the dispersing agent is a salt of an fattyacid, preferably having an average carbon number in the range of 10-20.In another example, the dispersing agent is a sulfonate, such as analkylbenze sulfonate having an average carbon number in the range of8-16, or an—α-olefin sulfonate having an average carbon number in therange of 10-20. In a preferred embodiment, the aqueous processingsolution 142 is heated to a predetermined value between 40 C to 60 C.

In a preferred configuration, the main processing unit 102 includes amechanical cleaning system 160 to aid in removing the unexposedphotopolymer from the photosensitive printing plate 20. The mechanicalcleaning system 160 typically includes one or more brushes which contactthe photopolymer layer 22 of photosensitive printing plate 20 while itis in contact with the aqueous processing solution 142. The brushes arepreferably moved relative to the photosensitive printing plate 20, forexample in a side-to-side motion or an orbital motion.

Various brush configurations can be used in accordance with the presentinvention. For example, the brushes can be downward facing as shown inFIG. 2. Examples of downward-facing brush configuration are shown inEuropean Patent No. 0586483B1, European Patent No. 0586470B1, and U.S.Pat. No. 8,444,333 (Suzuki et al.), each of which is incorporated hereinby reference. Alternatively, the brushes can be upward facing such as inthe configurations described in U.S. Pat. No. 5,124,736 (Yamamoto etal.) and U.S. Pat. No. 6,247,856 (Shibano et al.), each of which areincorporated herein by reference.

A collection system 144 is used to collect the used aqueous processingsolution 143 and return it to the processing solution tank 140 through aconduit 146. The used aqueous processing solution 143 will contain thephotopolymer that was removed from the unexposed portions 126 of thephotopolymer layer 22. The used aqueous processing solution 143 ispreferably passed through a filter 148 to remove larger particles of theremoved photopolymer. In an exemplary embodiment, the filter 148 is acoarse fabric-type filter material having a pore size of about 100 μmsimilar to that described in WO 2014/114900 A2 (Danon), entitled“Processing waste washout liquid.” In some configurations, the filter148 is supplied in a roll format, and the filter material is advancedduring operation of the processing system 100 to provide fresh filtermaterial. The used filter material containing the photopolymer particlesis collected on a take-up roll.

The main processing unit 102 removes the majority of the unexposedphotopolymer from the photosensitive printing plate 20 to provide therelief image 30. However, it has been observed that debris 128 istypically present on the surface of the relief image 30. The debris 128is primarily made up of residual particles of photopolymer that were notwashed off the surface of the photosensitive printing plate 20.

A secondary processing unit 104 is used to wash the developed reliefimage 30 with a secondary aqueous processing solution 152 supplied froma supply tank 150 to remove the remaining debris 128. The secondaryprocessing unit 104 can also be referred to as a secondary processingstation, a secondary developing unit/station or a washing unit/station.Preferably, a pump 114 is used to direct the secondary aqueousprocessing solution 152 onto the photosensitive printing plate 20 underpressure, bringing it into contact with the developed relief image 30.

In a preferred embodiment, an optional mechanical cleaning system 162,such as a rotating brush, is used to enhance the performance of thesecondary processing unit 104 by supplementing the washing action of thesecondary aqueous processing solution 152 with mechanical cleaning.

Some prior art systems, utilize a water rinsing operation to clean thesurface of the developed relief image 30. However, rather than being asimple water rinse, the secondary aqueous processing solution 152 usedin the secondary processing unit 104 of the present invention includesan active ingredient (i.e., a dispersing agent) to aid in the removal ofthe debris 128. The secondary aqueous processing solution 152 is unused,meaning that it has not previously been used to process a photosensitiveprinting plate 20 and therefore contains no photopolymer. It has beenfound that this substantially improves the effectiveness of removing thedebris 128. In a preferred embodiment the secondary aqueous processingsolution temperature is between 40 C-55 C.

Any appropriate dispersing agent can be used in the secondary aqueousprocessing solution 152 such as those that were discussed earlierrelative to the aqueous processing solution 142. In an exemplaryconfiguration, the dispersing agent in the secondary aqueous processingsolution 152 is the same as the dispersing agent used in the aqueousprocessing solution 142 used in the main processing unit 102. In otherconfigurations, the dispersing agent in the secondary aqueous processingsolution 152 can be different than the dispersing agent used in theaqueous processing solution 142.

In an exemplary configuration, the concentration of the dispersing agentin the secondary aqueous processing solution 152 is the same as theinitial concentration of the dispersing agent in the aqueous processingsolution 142 used in the main processing unit 102. In otherconfigurations, the concentration of the dispersing agent in thesecondary aqueous processing solution 152 can be greater than (or lessthan) than the concentration of the dispersing agent in the aqueousprocessing solution 142.

A collection system 154 collects the used secondary aqueous processingsolution 153 from the secondary processing unit 104 and directs it intothe processing solution tank 140 through a conduit 156. This has theadvantage that it replenishes the used aqueous processing solution 143that can contain large amounts of photopolymer with the fresher usedsecondary aqueous processing solution 153 from the secondary processingunit 104 which will contain only small amounts of photopolymer (i.e.,the removed debris 128).

A processing solution removal system 105 is used to remove aqueousprocessing solution 142 from the processing solution tank 140 and directit into a holding tank 180. This enables the volume of the aqueousprocessing solution 142 in the processing solution tank 140 to bemaintained below a predefined maximum volume as the used secondaryaqueous processing solution 153 is added to the processing solution tank140. In an exemplary configuration, the processing solution removalsystem 105 uses a pump 116 to pump the aqueous processing solution 142from the processing solution tank 140 into the holding tank 180.Preferably, the amount of aqueous processing solution 142 removed fromthe processing solution tank 140 is equal to the amount of usedsecondary aqueous processing solution 153 that is added to theprocessing solution tank 140 so that the total volume of aqueousprocessing solution 142 in the processing solution tank 140 remainsapproximately constant. In some embodiments, the pump 116 is operated ona predefined schedule (e.g., after processing each photosensitiveprinting plate 20). In other embodiments, the pump 116 can be operatedwhen it is detected that the volume of aqueous processing solution 142in the processing solution tank 140 is detected to exceed a predefinedthreshold.

The removal of the aqueous processing solution 142 by the processingsolution removal system 105 in combination with the addition of the usedsecondary aqueous processing solution 153 from the secondary processingunit 104 enables the concentration of photopolymer in the aqueousprocessing solution 142 in the processing solution tank 140 to bemaintained below a predefined maximum photopolymer concentration.Without this replenishment process, it has been found that theconcentration of the photopolymer in the aqueous processing solution 142in the processing solution tank 140 quickly builds up to an unacceptablelevel which detrimentally effects the performance of the processingsystem 100 after only processing a few (e.g., five or less)photosensitive printing plates 20. However, using the describedreplenishment process it has been found that acceptable performance canbe maintained even after processing a large number (e.g., more than 50)photosensitive printing plates 20.

The aqueous processing solution 142 operates optimally within a definedpH range. The presence of the photopolymer in the used aqueousprocessing solution 143 can change the pH of the solution therebyreducing its effectiveness. The described process including the removalof the aqueous processing solution 142 by the processing solutionremoval system 105 in combination with the addition of the usedsecondary aqueous processing solution 153 from the secondary processingunit 104 enables the pH of the aqueous processing solution 142 in theprocessing solution tank 140 to be maintained within a predefinedacceptable pH range for processing a larger number of photosensitiveprinting plates 20.

In the exemplary processing system 100, after the photosensitiveprinting plate 20 has been processed by the secondary processing unit104, it is rinsed using a rinsing unit 106 which directs a stream ofwater 170 onto the surface of the developed relief image 30. This waterrinsing is used to remove any residual processing solution from thesurface of the photosensitive printing plate 20. The photosensitiveprinting plate 20 is then dried using a drying unit 108. In an exemplaryconfiguration, the drying unit 108 uses an air knife 172 to direct astream of air onto the surface of the developed relief image 30.

At some point it is necessary to discard the waste processing solution181 collected in the holding tank 180. In an exemplary configuration, acoagulant supply system 182 can be used to add an appropriate coagulant184 to the waste processing solution 181 to coagulate the polymer in thewaste processing solution 181. The resulting solid coagulated polymer186 can then be removed from the solution and discarded in anappropriate manner. The remaining waste processing solution 181 can thenbe disposed of in most locations without any significant environmentalconcerns. Examples of coagulants 184 that can be used to produce thecoagulated polymer 186 include Bentonite clay (such as commerciallyavailable RM-10 from Cetco), Alum (potassium aluminum sulphate),aluminum sulphate, strong acids (such as hydrochloric acid), ferricchlorides, and many other chemicals commonly used in waste watertreatment. Bentonite Clay RM-10 is particularly preferred.

The effectiveness of the described processing method was tested byprocessing a series of photosensitive printing plates 20 and evaluatingthe results for artifacts. The photosensitive printing plates 20 were ofa type similar to those described in the aforementioned U.S. Pat. No.8,492,449 (Inoue et al.) (except that no antiadhesive layer is includedover the photopolymer layer), and were 35×47 inches in size. Thephotosensitive printing plates 20 were exposed using the methoddescribed with respect to FIGS. 1A-1C to provide photosensitive printingplates 20 with latent images 28 corresponding to typical image content.The photosensitive printing plates 20 were then processed using anaqueous processing solution 142 for 3.5 minutes at 50° C. to remove theunexposed photopolymer, together with mechanical cleaning as describedearlier. The used aqueous processing solution 143 containing the removedphotopolymer was then returned to the processing solution tank 140 afterfiltering as discussed earlier with respect to FIG. 2. For this testing,the dispersing agent in the aqueous processing solution 142 was acommercially-available dishwashing detergent from Miyoshi SoapCorporation, whose active ingredients are salts of various long chainfatty acids. At various intervals, the processed photosensitive printingplates 20 were evaluated to determine the number of debris artifacts intwo size ranges (≥12 μm and ≥50 μm).

FIG. 3A shows a table 200 summarizing the experimental results for abaseline test corresponding to a configuration where the same aqueousprocessing solution 142 (drawn from the processing solution tank 140)was used for both the main processing unit 102 and the secondaryprocessing unit 104. The first column of the table 200 shows the numberof processed photosensitive printing plates 20. The row for Plate #0corresponds to the initial state before any plates were processed.

The second column of the table 200 shows the amount of dispersing agentin the aqueous processing solution 142 in the processing solution tank140. In this example, the amount of dispersing agent stays at a constantlevel since no processing solution was added or removed from theprocessing solution tank 140.

Since the secondary processing unit 104 used the same aqueous processingsolution 142 as the main processing unit 102, no secondary aqueousprocessing solution 152 was used as indicated by the “N/A” in the thirdcolumn. The fourth column indicates that 12 liters of processingsolution (in this case aqueous processing solution 142) was used by thesecondary processing unit 104 to process each photosensitive printingplate 20. (The secondary processing unit 104 used 6 liters/minute for 2minutes corresponding to the total solution volume of 12 liters.)

Over time, as more photosensitive printing plates 20 were processed, itcan be seen that the amount of polymer in the processing solution tank140 grew steadily (see column #5), as well as the ratios of the polymerto the dispersing agent (see column #6). The pH of the aqueousprocessing solution 142 in the processing solution tank 140 wasgradually reduced over time (see column #7), which will have the resultof decreasing the effectiveness of the processing.

The processed photosensitive printing plates 20 were dried, and postexposed in a conventional UV exposure and finishing process. Thefinished plates were then evaluated under a microscope to analyzedefects related to debris particles measured at random locations on theplate. It can be seen that even after just processing fivephotosensitive printing plates 20, a significant number of debrisartifacts were detected (see columns #8 and #9). Even a single largedebris artifact would be unacceptable, so in the prior artconfiguration, the aqueous processing solution 142 would need to bediscarded after processing less than five plates. Furthermore, theoverall quality of cleanliness of the processing system (as evidenced byparticulates attached to the sides of the machine, and on the brushsurface) was evaluated (see column #10), and was found to declinerapidly.

FIGS. 3B-3D show results obtained according to the method of the presentinvention where the secondary aqueous processing solution 152 used bythe secondary processing unit 104 is fresh solution that includes adispersing agent, and where the used secondary aqueous processingsolution 153 is added to the processing solution tank 140. In theseexamples, the amount of aqueous processing solution 142 removed from theprocessing solution tank 140 was equal to the amount of used secondaryaqueous processing solution 153 that was added to the processingsolution tank 140 so that the total volume of aqueous processingsolution 142 in the processing solution tank 140 remained approximatelyconstant.

In Example #1 summarized in table 210 of FIG. 3B, the concentration ofthe dispersing agent in the used secondary aqueous processing solution153 (see column #3) is about 2× the initial concentration of the aqueousprocessing solution 142 in the processing solution tank 140 (see column#2). In this example, the secondary processing unit 104 used 7.5liters/minute of used secondary aqueous processing solution 153 for 2minutes for a total of 15 liters.) From column #2, it can be seen thatover time, the concentration of dispersing agent in the aqueousprocessing solution 142 in the processing solution tank 140 graduallyincreases due to the addition of the used secondary aqueous processingsolution 153, which has a higher dispersing agent concentration.

While the amount of polymer in the processing solution tank 140 (seecolumn #5) increases over time, it does so at a much lower rate than itdid in the prior-art configuration of FIG. 3A. Likewise, the ratio ofthe polymer to the dispersing agent (see column #6) also grows much moreslowly. The pH of the aqueous processing solution 142 remainsapproximately constant in this case. The performance of the processingsystem 100 is substantially improved relative to the prior art as can beseen by the number of debris artifacts (see columns #8 and 9) and theprocessing system cleanliness (see column 10). Even after processing 49printing plates, the number of debris artifacts was at an acceptablelevel.

The data of FIG. 3B demonstrates that the improved processing system 100has the advantage that it can be operated for much longer periods oftime before requiring that the aqueous processing solution 142 in theprocessing solution tank 140 be replaced with fresh solution. Whereasthe prior art configuration of FIG. 3A could only be used to process afew printing plates, it has been found to be possible to process as manyas 50 or more printing plates with the improved processing system 100.

FIG. 3C shows a table 220 summarizing the results obtained for analternate configuration where the concentration of the dispersing agentin the used secondary aqueous processing solution 153 (see column #3) isthe same as the initial concentration of the aqueous processing solution142 in the processing solution tank 140 (see column #2, plate #0). As aresult, the concentration of the dispersing agent in the aqueousprocessing solution 142 (see column #2) stays constant over time. The pHdecreased slightly (see column #7) over time. In this case, no debrisartifacts were found after processing 16 plates (see columns #8 and 9),and the overall system cleanliness was very good (see column 10).

FIG. 3D shows a table 230 summarizing the results obtained for analternate configuration where the concentration of the dispersing agentin the secondary aqueous processing solution 153 (see column #3) isabout 3× the initial concentration of the aqueous processing solution142 in the processing solution tank 140 (see column #2, plate #0). Inthis case, the flow rate of the used secondary aqueous processingsolution 153 was reduced to 5 liters/minute for 2 minutes so that atotal of 10 liters of used secondary aqueous processing solution 153were used (see column #4). (Below this flow rate, it was found that theused secondary aqueous processing solution 153 did not fully cover theplate for the tested configuration of the secondary processing unit 104.The minimum flow rate needed to fully cover the plate may vary dependingon the size of the plate, and the type of active ingredient in the usedsecondary aqueous processing solution 153.) For this example, it can beseen that the concentration of the dispersing agent in the aqueousprocessing solution 142 (see column #2) gradually increased over time,and the pH increased slightly (see column #7). In this case, only asingle small debris artifact was found after processing 16 plates (seecolumns #8 and 9), and the overall system cleanliness was excellent (seecolumn 10).

Several finished photosensitive printing plates 20 corresponding to thetested configurations shown in FIGS. 3A-3D were also used to make printsin a flexographic printing press in order to analyze visible printdefects corresponding to the debris on the photosensitive printingplates 20. It was found that visual mottle appearance and voids on theprinted substrate increased with the number of debris particles andlarger sizes of debris on the plate as would be expected. Samples fromthe comparative prior art example of FIG. 3A showed visible printdefects only after processing only a few plates. In comparison, thephotosensitive printing plates 20 processed in accordance with thepresent invention according to the exemplary configurations of FIG.3B-3D showed no visible print defects resulting from debris particles onthe plate.

Without excluding other reasonable explanations, it is hypothesized thatthe inventive plate processing method helps to more effectively cleanthe entire surface of the photosensitive printing plates 20 due to theaddition of the active ingredient to the secondary aqueous processingsolution 152 used in the secondary processing unit 104. Furthermore, theaddition of the used secondary aqueous processing solution 153 includingthe dispersing agent to the processing solution tank 140, and theremoval of a portion of the used aqueous processing solution 143 fromthe processing solution tank 140 results in lower polymer concentrationsand lower ratios of polymer to dispersing agent in the processingsolution tank 140. This is believed to reduce the agglomeration of thepolymer particles, while maintaining the pH in a desirable range.

The invention has been described in detail with particular reference tocertain preferred embodiments thereof, but it will be understood thatvariations and modifications can be effected within the spirit and scopeof the invention.

PARTS LIST

-   10 mask material-   12 mask layer-   14 substrate-   16 radiation-   18 mask image-   20 photosensitive printing plate-   22 photopolymer layer-   24 substrate-   26 radiation-   28 latent image-   29 cross-linked polymer region-   30 relief image-   100 processing system-   101 processing path-   102 main processing unit-   104 secondary processing unit-   105 processing solution removal system-   106 rinsing unit-   108 drying unit-   110 platen-   112 pump-   114 pump-   116 pump-   124 exposed portions-   126 unexposed portions-   128 debris-   140 processing solution tank-   142 aqueous processing solution-   143 used aqueous processing solution-   144 collection system-   146 conduit-   148 filter-   150 supply tank-   152 secondary aqueous processing solution-   153 used secondary aqueous processing solution-   154 collection system-   156 conduit-   160 mechanical cleaning system-   162 mechanical cleaning system-   170 water-   172 air knife-   180 holding tank-   181 waste processing solution-   182 coagulant supply system-   184 coagulant-   186 coagulated polymer-   200 table-   210 table-   220 table-   230 table

1. A system for processing a photosensitive flexographic printing platehaving a latent image formed by image-wise exposure of anaqueous-processable photopolymer, comprising: a platen for receiving thephotosensitive flexographic printing plate having the latent image thathas at least one exposed portion with hardened photopolymer and at leastone unexposed portion with unhardened photopolymer; a main processingunit for forming a relief image from the latent image, the mainprocessing unit comprising: a pump for contacting a first aqueousprocessing solution including a first dispersing agent with the latentimage; a mechanical cleaning system including one or more brushes formechanically cleaning the latent image in the presence of the firstaqueous processing solution; and a collection system for collecting afirst used aqueous processing solution having the photopolymer; asecondary processing unit comprising: a second pump for washing therelief image with a second aqueous processing solution including asecond dispersing agent, the second aqueous processing solution beingdevoid of the photopolymer; and a second collection system forcollecting a second used aqueous processing solution having thephotopolymer; a processing solution tank fluidly coupled to thecollection system and the second collection system and configured tocombine the first used aqueous processing solution with the second usedaqueous processing solution to form a combined used aqueous processingsolution; a processing solution removal system fluidly coupled with theprocessing solution tank, the processing solution removal systemcomprising: a holding tank configured for receiving the combined usedaqueous processing solution; and a conduit from the processing solutiontank to the holding tank, wherein the processing solution tank includesthe combined used aqueous processing solution at less than a predefinedmaximum volume and having the photopolymer at less than a predefinedmaximum concentration.
 2. The system of claim 1, wherein the secondaryprocessing unit includes a second mechanical cleaning system having oneor more second brushes.
 3. The system of claim 1, further comprising afilter between: the main processing unit and processing solution tank;and the secondary processing unit and the processing solution tank. 4.The system of claim 1, further comprising a rinsing unit having water,wherein the rising unit is positioned in a processing path after thesecondary processing unit.
 5. The system of claim 1, wherein theprocessing solution removal system further comprises a coagulant supplysystem having a coagulant for the photopolymer.
 6. The system of claim1, further comprising: the secondary processing unit including a secondmechanical cleaning system including one or more second brushes; afilter between the main processing unit and processing solution tank,and a filter between the secondary processing unit and the processingsolution tank; a rinsing unit having water, wherein the rising unit ispositioned in a processing path after the secondary processing unit; andthe processing solution removal system including a coagulant supplysystem having a coagulant for the photopolymer.
 7. The system of claim1, wherein the system is adapted such that a first latent image iscontacted with the first aqueous processing solution with or without thephotopolymer and a subsequent latent image is contacted with thecombined used aqueous processing solution as the first aqueousprocessing solution.
 8. The system of claim 1, wherein the firstdispersing agent is the same as the second dispersing agent.
 9. Thesystem of claim 1, wherein the processing solution tank includes thecombined used aqueous processing solution within a predefined pH range.10. The system of claim 1, further comprising a coagulant in theprocessing solution tank.
 11. The system of claim 1, further comprisinga coagulant supply operably coupled to the processing solution tank. 12.The system of claim 1, further comprising at least one temperaturecontroller configured for: maintaining the first aqueous processingsolution and combined aqueous processing solution at a temperaturebetween 40° C. to 60° C.; and/or maintaining the second aqueousprocessing solution at a temperature between 40° C. to 55° C.
 13. Thesystem of claim 1, further comprising a dryer adapted to dry the washedrelief image.
 14. The system of claim 1, further comprising an UV lightadapted to irradiate the UV light.
 15. The system of claim 1, whereinthe first dispersing agent is different from the second dispersingagent.
 16. The system of claim 1, wherein the system is adapted tomaintain the combined used aqueous processing solution below thepredefined maximum volume.
 17. The system of claim 16, wherein thesystem is adapted to maintain the concentration of the photopolymer inthe combined used aqueous processing solution below the predefinedmaximum photopolymer concentration.
 18. The system of claim 7, whereinthe system is adapted to: maintain the combined used aqueous processingsolution below the predefined maximum volume; and maintain theconcentration of the photopolymer in the combined used aqueousprocessing solution below the predefined maximum photopolymerconcentration.
 19. A method for processing a photosensitive flexographicprinting plate having a latent image formed by image-wise exposure of anaqueous-processable photopolymer, comprising: providing the system ofclaim 1; contacting a first latent image with the first aqueousprocessing solution with or without the photopolymer and obtaining firstused aqueous processing solution; contacting the relief image of thefirst latent image with the second aqueous processing solution withoutphotopolymer and obtaining second used aqueous processing solution;combining the first used aqueous processing solution with the secondused aqueous processing solution to form the combined used aqueousprocessing solution; maintaining the combined used aqueous processingsolution below the predefined maximum volume; maintaining theconcentration of the photopolymer in the combined used aqueousprocessing solution below the predefined maximum photopolymerconcentration; and contacting a subsequent latent image with thecombined used aqueous processing solution as the first aqueousprocessing solution.
 20. The method of claim 19, further comprising:adding a coagulant to the combined aqueous processing solution tocoagulate the photopolymer; and removing the coagulated photopolymerfrom the combined aqueous processing solution.